Certainly, here are 10 luxury watch brands that are known to produce timepieces even more expensive than Rolex:

Patek Philippe: Renowned for their intricate craftsmanship and exceptional complications, Patek Philippe watches are often considered some of the most valuable and expensive in the world.

A. Lange & Söhne: A German brand celebrated for its exquisite detailing and precision, A. Lange & Söhne watches are highly sought after by collectors.

Audemars Piguet: Famous for their Royal Oak and Royal Oak Offshore models, Audemars Piguet creates luxurious and avant-garde timepieces that command high prices.

https://www.premiumluxurywatch.com/product-category/audemars-piguet/

Richard Mille: Known for their innovative designs and use of advanced materials, Richard Mille watches often feature complex mechanisms and are favored by celebrities and athletes.

Vacheron Constantin: With a rich history dating back to 1755, Vacheron Constantin produces elegant and timeless watches that are admired for their artistry and craftsmanship.

Jaeger-LeCoultre: Renowned for their intricate movements and elegant designs, Jaeger-LeCoultre watches are celebrated for their blend of technical innovation and aesthetics.

Greubel Forsey: This brand is acclaimed for its exceptional tourbillon watches and its commitment to pushing the boundaries of watchmaking complexity.

F.P. Journe: François-Paul Journe’s watches are known for their innovative movements and limited production, contributing to their high value among collectors.

Ulysse Nardin: Notable for its marine chronometers and avant-garde designs, Ulysse Nardin offers a range of luxurious and distinctive timepieces.

Hublot: Recognized for its fusion of materials and bold designs, Hublot creates watches that appeal to those seeking modern and unique luxury timepieces.

https://www.premiumluxurywatch.com/product-category/hublot/

Keep in mind that the prices of watches from these brands can vary widely based on factors such as materials used, complications, limited editions, and more. Additionally, the luxury watch brands market is dynamic, so prices may have changed since my last knowledge update in September 2021.